https://doi.org/10.1140/epjp/s13360-025-06534-3
Comment
Comment on “Eigensolution, expectation values and thermodynamic properties of the screened Kratzer potential”
INIFTA, DQT, Sucursal 4, C. C. 16, 1900, La Plata, Argentina
a
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Received:
26
May
2024
Accepted:
9
June
2025
Published online:
22
June
2025
Abstract
We show that the parameters
and
in the screened Kratzer potential are not the actual equilibrium bond length and dissociation energy, respectively. Consequently, it makes no sense to apply this form of the model to the spectroscopy of diatomic molecules. We prove that the calculation of the canonical partition function is incorrect because the authors omitted the sum over the rotational quantum number. For this reason, the resulting thermodynamic functions are of no practical utility whatsoever.
© The Author(s), under exclusive licence to Società Italiana di Fisica and Springer-Verlag GmbH Germany, part of Springer Nature 2025

