https://doi.org/10.1140/epjp/s13360-024-05757-0
Regular Article
Effect of pre-annealing temperature on electrochemical corrosion performance of the Au50Ag25Pd25 alloy in human artificial saliva
1
Department of Physics and Microelectronics, Zhengzhou University, Zhengzhou, China
2
Institute of Physics, Bahauddin Zakariya University, Multan, Pakistan
b
munamkhan255@gmail.com
c
amerziya@gmail.com
Received:
18
July
2024
Accepted:
18
October
2024
Published online:
29
October
2024
Au–Ag–Pd alloys are extensively applied in dentistry due to their excellent mechanical properties, high corrosion resistance, and biocompatibility. This research carried out to determine the effect of pre-annealing on electrochemical corrosion by using electrochemical techniques such as open-circuit potential (OCP), electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization (PDP). The Au50Ag25Pd25 alloy samples were annealed at 750 °C, 800 °C, and 900 °C. It was observed that as the pre-annealing temperature rises, the corrosion resistance steadily decreases because of the chemical inhomogeneity on the sample surfaces. Comparing the non-annealed sample (SN) to pre-annealed samples (S3, S5, and S7), potentiodynamic polarization parameters show that the SN has a higher polarization resistance and a lower corrosion current density. Imaging from scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS) reveals that the sample surface forms oxide films that become thinner with increase in pre-annealing temperature. These results provide insight into the behavior of corrosion of Au–Ag–Pd alloys and can help optimize their performance in dental applications.
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© The Author(s), under exclusive licence to Società Italiana di Fisica and Springer-Verlag GmbH Germany, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.