Removal of Cd(II) and Pb(II) ions from water solution by CoFeO/AlO nanocomposite

Ashwini S. Varpe; Mrinalini D. Deshpande; Dipak R. Tope; Ashok V. Borhade

doi:10.1140/epjp/s13360-022-02898-y

2024 Impact factor 2.9

EPJ PLUS - Condensed Matter and Complex Systems

Eur. Phys. J. Plus (2022) 137: 705
https://doi.org/10.1140/epjp/s13360-022-02898-y

Regular Article

Removal of Cd(II) and Pb(II) ions from water solution by CoFe $_{2}$ $_{2}$ O $_{4}$ $_{4}$ /Al $_{2}$ $_{2}$ O $_{3}$ $_{3}$ nanocomposite

Ashwini S. Varpe¹, Mrinalini D. Deshpande¹^b, Dipak R. Tope² and Ashok V. Borhade²

¹ Department of Physics, H.P.T. Arts and R.Y.K. Science College, 422005, Nashik, Maharashtra, India
² Department of Chemistry, H.P.T. Arts and R.Y.K. Science College, 422005, Nashik, Maharashtra, India

^b d_mrinal@yahoo.com

Received: 27 January 2022
Accepted: 28 May 2022
Published online: 17 June 2022

Abstract

In this study, the performance of magnetic CoFe $_{2}$ $_{2}$ O $_{4}$ $_{4}$ /Al $_{2}$ $_{2}$ O $_{3}$ $_{3}$ nanocomposite is evaluated towards the removal of Cd(II) and Pb(II) metal ions from the wastewater. The removal efficiency of CoFe $_{2}$ $_{2}$ O $_{4}$ $_{4}$ /Al $_{2}$ $_{2}$ O $_{3}$ $_{3}$ nanocomposite is compared with the bare CoFe $_{2}$ $_{2}$ O $_{4}$ $_{4}$ nanoparticles. The CoFe $_{2}$ $_{2}$ O $_{4}$ $_{4}$ and its composite with Al $_{2}$ $_{2}$ O $_{3}$ $_{3}$ is synthesized via sol–gel auto-combustion method. The as-prepared samples are characterized by fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscope (TEM) and vibrating sample magnetometer (VSM) analysis. As compared to bare nanoparticles, the decrease in particle size, enhanced specific surface area and porosity, higher magnetization, lowering of the band gap, and uniform distribution with spherical shaped structure is observed in CoFe $_{2}$ $_{2}$ O $_{4}$ $_{4}$ /Al $_{2}$ $_{2}$ O $_{3}$ $_{3}$ nanocomposite. To probe the nature of the adsorbent, various experiments are performed by considering the reaction parameters like contact time, adsorbent dose and concentration of Cd(II) and Pb(II) ions. During optimization process, it is observed that for bare CoFe $_{2}$ $_{2}$ O $_{4}$ $_{4}$ nanoparticles, the maximum removal efficiency is found for Cd(II) ions 75% and for Pb(II) ions, it reaches upto 43%. In composite form, the removal efficiency for Cd(II) ions increases upto 88 $%$ $\%$ and for Pb(II) ions, it is 77%. The enhanced removal efficiency is observed for the CoFe $_{2}$ $_{2}$ O $_{4}$ $_{4}$ /Al $_{2}$ $_{2}$ O $_{3}$ $_{3}$ nanocomposite due to smaller particle size and increased surface area as compared to that of CoFe $_{2}$ $_{2}$ O $_{4}$ $_{4}$ nanoparticles. The effect on removal efficiency is also studied with the variation of temperature. The isothermal adsorption results are well fitted to Langmuir model. The high adsorption capacity of CoFe $_{2}$ $_{2}$ O $_{4}$ $_{4}$ /Al $_{2}$ $_{2}$ O $_{3}$ $_{3}$ nanocomposite as compared to CoFe $_{2}$ $_{2}$ O $_{4}$ $_{4}$ makes it promising candidate for removal of heavy metal ions from aqueous solution.