Eur. Phys. J. Plus (2020) 135: 40
https://doi.org/10.1140/epjp/s13360-019-00086-z

Regular Article

Magnetic and optical properties of Co-doped ZnO nanorod arrays

¹ College of Physics and Electronic Information, Yan’an University, Yan’an, People’s Republic of China
² College of Information Science and Technology, Northwest University, Xi’an, People’s Republic of China
³ School of Physics and Optoelectronic Engineering, Yangtze University, Jingzhou, 434023, People’s Republic of China
⁴ Communication and Information Engineering College, Xi’an University of Science and Technology, Xi’an, People’s Republic of China

^* e-mail: zhangfuchun72@163.com
^** e-mail: yanjf@nwu.edu.cn
^*** e-mail: zly512@163.com

Received: 23 July 2019
Accepted: 27 December 2019
Published online: 10 January 2020

Abstract

In this study, Zn_1−xCo_xO nanorod arrays were deposited on Si substrates by magnetron sputtering followed by the hydrothermal method at 100 °C. The effects of doping concentration and hydrothermal growth conditions on the crystal structures, morphologies, magnetic and optical properties of the obtained Zn_1−xCo_xO nanorod arrays were studied. Surface characterization showed Zn_1−xCo_xO nanorod arrays with uniform and dense distributions along the [0001] direction with the hexagonal wurtzite structure. Besides, no impurity phases were detected in Zn_1−xCo_xO nanorod arrays. The room-temperature ferromagnetism of Zn_1−xCo_xO nanorod arrays was detected based upon the high-saturation magnetization of 4.4 × 10^–4 emu/g, the residual magnetization of 1.1 × 10^–4 emu/g and the coercive field of 309 Oe. Furthermore, the photoluminescence (PL) spectra exhibited by the Zn_1−xCo_xO nanorod arrays with the luminescence intensity in the ultraviolet region were nearly five times that of the pure ZnO nanorod arrays. With the increase in the Co²⁺ doping concentration, the redshift in the ultraviolet emission peaks was observed. The theoretical results presented obvious spin polarization near the Fermi level, with strong Co 3d and O 2p hybridization effects. The magnetic moments were mainly generated by Co 3d and partial contribution of O 2p orbital electrons. These results indicated that Zn_1−xCo_xO nanorod arrays can be used as potential magneto-optical materials.